A process for treating sour water includes combining the sour water with an alkali or alkaline metal hydroxide to produce a sour water mixture, the sour water comprising sulfides, passing an electric current through the sour water mixture, where passing the electric current through the sour water mixture causes at least a portion of the sulfides to react to produce a treated sour water comprising sulfates and having a pH of 7.1 to 9.8, saturating the at least a portion of the sulfates in an aqueous sulfate solution, and separating at least a portion of saturated sulfates from a saturated aqueous sulfate solution.