The present invention relates to a window system provided with a blind for solar photovoltaic power generation. In the window system of the present invention, a blind provided with solar cells is installed in a space between indoor side windows and outdoor side windows slidably coupled to the inner surfaces of a window frame. With such a configuration, the window system is easy to install and maintain. The window system of the present invention includes a window frame 10; indoor side windows 21 and outdoor side windows 23 slidably coupled to the inner surfaces of the window frame 10; and a blind 100 for solar photovoltaic power generation installed in a space S between the indoor side windows 21 and the outdoor side windows 23.