There is disclosed a method of coating mammalian hair, the method comprising applying, on the external surface of individual hairs of the mammalian hair, an oil-in-water emulsion comprising: (i) an aqueous phase containing water; and (ii) an oil phase containing at least one water-insoluble reactive condensation-curable film-forming amino-silicone pre-polymer that, subsequent to condensation curing, forms an elastomer. The reactive oil phase may further contain a plurality of sub-micronic pigment particles dispersed therein. Suitable compositions and kits including the same are also disclosed, as well as methods for preparing the compositions.