A steel sheet mainly suitable for strength members of automobiles or building materials, which has a tensile strength of 1,180 MPa or more, and which is excellent in delayed fracture resistance and primary rust prevention performance. The steel sheet includes a coating, placed on a surface of a cold-rolled steel sheet with a tensile strength of 1,180 MPa or more, containing one or more metalates selected from molybdates and tungstates and a P compound. The sum of the coating weights of the metalates in terms of Mo and W is 10 mg/m2 to 1,000 mg/m2 and is preferably 50 mg/m2 to 1,000 mg/m2. The coating weight of the P compound in terms of P is 10 mg/m2 to 1,000 mg/m2.