- Patent Title: Nickel-manganese composite hydroxide, method for producing the same, positive electrode active material for nonaqueous electrolyte secondary battery, method for producing the same, and nonaqueous electrolyte secondary battery
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Application No.: US16320601Application Date: 2017-07-28
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Publication No.: US11296316B2Publication Date: 2022-04-05
- Inventor: Haruki Kaneda , Yuki Koshika , Takaaki Ando
- Applicant: SUMITOMO METAL MINING CO., LTD.
- Applicant Address: JP Tokyo
- Assignee: SUMITOMO METAL MINING CO., LTD.
- Current Assignee: SUMITOMO METAL MINING CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Westerman, Hattori, Daniels & Adrian, LLP
- Priority: JPJP2016-150505 20160729
- International Application: PCT/JP2017/027538 WO 20170728
- International Announcement: WO2018/021555 WO 20180201
- Main IPC: H01M4/505
- IPC: H01M4/505 ; H01M4/525 ; C01G53/00 ; C01G53/04 ; H01M10/0525 ; H01M4/86

Abstract:
Provided are a positive electrode active material with which a nonaqueous electrolyte secondary battery having a high energy density can be obtained, a nickel-manganese composite hydroxide suitable as a precursor of the positive electrode active material, and production methods capable of easily producing these in an industrial scale. Provided is a nickel-manganese composite hydroxide represented by General Formula (1): NixMnyMz(OH)2+α and containing a secondary particle formed of a plurality of flocculated primary particles. The nickel-manganese composite hydroxide has a half width of a diffraction peak of a (001) plane obtained by X-ray diffraction measurement of at least 0.10° and up to 0.40° and has a degree of sparsity/density represented by [(void area within secondary particle/cross section of secondary particle)×100](%) of at least 0.5% and up to 10%. Also provided is a production method of the nickel-manganese composite hydroxide.
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