An electrode structure includes a first electrode unit, a second electrode unit and a first insulating frame, in which the electrode units are adjacent to each other. The first insulating unit has an airflow space therein and includes an electrically conducive base with an airflow plane and an air cell cathode disposed on an outer surface of the airflow plane. The second insulating unit includes an electrically conductive base and an air cell anode disposed on an outer surface of the electrically conductive base. The first insulating frame spaces and joins the adjacent electrode units to each other such that the air cell cathode and the air cell anode of the adjacent electrode units are opposed to each other. The first insulating frame together with the adjacent electrode units forms an electrolytic solution container.