The present invention relates to an air conditioner for a vehicle having a rear seat outlet, which can relieve temperature inversion that discharge temperature of the console vent becomes higher than discharge temperature of a rear seat floor vent in a bi-level mode, and prevent reduction of air volume of the console vent in the cooling mode. The air conditioner for a vehicle, which has a rear seat outlet, includes an air-conditioning case having an air passageway formed therein and a plurality of air outlets, and a cooling heat exchanger and a heating heat exchanger disposed in the air passageway of the air-conditioning case to exchange heat with air passing through the air passageway. Wherein the air outlets include a console vent and a rear seat floor vent, and an entrance of the rear seat floor vent is formed above an entrance of the console vent.