A solid-state battery cell includes a cathode comprising a cathode glass fiber scaffold impregnated with cathode active material, an anode comprising an anode glass fiber scaffold impregnated with lithium metal or a lithium metal alloy, and a first electrolyte layer comprising an electrolyte glass fiber scaffold impregnated with a first solid-state electrolyte, the electrolyte layer positioned between the cathode and the anode and the electrolyte glass fiber scaffold extending throughout the first electrolyte layer.