The invention relates to a polyolefin film comprising at least five layers: a core layer (a), comprising a polyolefin; an outer supporting layer (b), comprising copolymers of ethylene and propylene; an inner supporting layer (c), on the face of the core layer opposite to the outer supporting layer, comprising a polyolefin; a first coating layer (d) immediately in contact with the inner supporting layer (c), and finally a second coating layer (e) immediately in contact with the inner supporting layer (c), both comprising copolymers of ethylene with one or several polar monomers. In addition, the present invention relates to the process of manufacturing said polyolefin film and also the uses thereof for coating a substrate.