The present disclosure relates to a process by which an optical fiber is terminated with a ferrule to form an optical fiber connector assembly. The ferrule is heated at a heating temperature whereby the ferrule bore (and ferrule microhole) expands. The optical fiber is then inserted into the ferrule microhole. The ferrule then contracts when heat is no longer applied resulting in an interference fit between the optical fiber and the ferrule microhole based on the dimensions of the optical fiber and the ferrule microhole. The interference fit yields certain optical fiber characteristics within the optical fiber connector assembly. The present disclosure also relates to an optical fiber having an outer cladding comprising titania-doped silica and the resulting optical fiber characteristics.