A liquid storage vessel having a base with a bottom and an interior floor; a continuous side extending vertically from the base and having an interior surface, the bottom and continuous side each including an internal layer and an external layer separated by a material barrier, and configured such that the interior layers form an inner containment liner, and the external layers form a continuous exterior structural shell enclosing the inner containment liner. A top is affixed to the continuous side and has an interior ceiling. Access to the tank interior is provided by one or more manways. Mounting and connecting structures enable the tanks to be stacked directly atop one another and then structurally connected. The exterior structural shell is fabricated from high performance fiber reinforced concrete, and the inner containment liner is fabricated from a geopolymer concrete blend.