A superhydrophobic polypropylene porous film, including a polypropylene porous film substrate, titanium dioxide layers and a surface modifier layer, is disclosed. The titanium dioxide layers are deposited on the surface of the polypropylene porous film substrate by atomic deposition technology; a surface modifier is coated on the titanium dioxide layers; hydrophobic bonds are formed between the titanium dioxide layers and the surface modifier layer; the superhydrophobic polypropylene porous film has a water contact angle greater than 150 degrees, a rolling angle less than 10 degrees, an aperture of 0.1-0.4 μm, a porosity of 50%-80%, a tensile strength of 30-50 MPa, and an elongation at break of 10%-30%. The superhydrophobic polypropylene porous film maintains the chemical resistance, rigidity, and porosity of the polypropylene porous film, and has superhydrophobic properties and a good separation effect after working for 80 hours, thus greatly increasing the service life, and reducing operation costs and working costs in a membrane distillation process.