Invention Grant
- Patent Title: Process for the production of 1,4-butanediol from renewable sources and polyesters obtained therefrom
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Application No.: US16766498Application Date: 2018-11-27
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Publication No.: US11377409B2Publication Date: 2022-07-05
- Inventor: Marco Cotti Comettini , Roberto Vallero , Catia Bastioli , Luigi Capuzzi
- Applicant: NOVAMONT S.P.A
- Applicant Address: IT Novara
- Assignee: NOVAMONT S.P.A
- Current Assignee: NOVAMONT S.P.A
- Current Assignee Address: IT Novara
- Agency: Polsinelli PC
- Priority: IT102017000135678 20171127
- International Application: PCT/EP2018/082668 WO 20181127
- International Announcement: WO2019/102030 WO 20190531
- Main IPC: C07C29/80
- IPC: C07C29/80 ; B01D3/00 ; B01D15/00 ; C08G18/00 ; C07C29/76 ; B01D3/14 ; B01D15/36 ; C07C31/20 ; C08G18/42 ; C08G63/181 ; C08J5/18 ; C08L67/02 ; C12P7/18

Abstract:
The invention relates to a process for the production of 1,4-butanediol comprising the preparation of a fermentation broth comprising 1,4-butanediol from renewable sources and water, separation of a liquid fraction comprising said 1,4-butanediol and water from one or more solid fractions, said liquid fraction comprising 2-pyrrolidone in an amount higher than 80 ppm, one or more passages of the resulting liquid fraction through a bed comprising one or more cation-exchange resins thereby providing an output pH of said liquid fraction from 4 to 2, one or more passages of the resulting liquid fraction through a bed comprising one or more anion-exchange resins thereby providing an output pH of said liquid fraction from 8 to 11, and the distillation of the liquid fraction thereby provided so as to obtain a composition having a concentration of said 1,4-butanediol higher than 99.0% by weight and comprising 2-pyrrolidone in an amount lower than 6 ppm. The resulting composition should exhibit an APHA color value after ageing of less than 30.
Public/Granted literature
- US20200377437A1 PROCESS FOR THE PRODUCTION OF 1,4-BUTANEDIOL FROM RENEWABLE SOURCES AND POLYESTERS OBTAINED THEREFROM Public/Granted day:2020-12-03
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