Invention Grant
- Patent Title: Carbonate precursors for lithium nickel manganese cobalt oxide cathode material and the method of making same
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Application No.: US15517276Application Date: 2015-09-30
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Publication No.: US11380882B2Publication Date: 2022-07-05
- Inventor: Jin Hu , HeonPyo Hong , Jens Paulsen , JinDoo Oh , Daniël Nelis , Eric Robert
- Applicant: Umicore , Umicore Korea LTD
- Applicant Address: BE Brussels; KR Chungnam
- Assignee: Umicore,Umicore Korea LTD
- Current Assignee: Umicore,Umicore Korea LTD
- Current Assignee Address: BE Brussels; KR Chungnam
- Agency: NK Patent Law
- Priority: EP14188028 20141008,EP15164468 20150421
- International Application: PCT/IB2015/057491 WO 20150930
- International Announcement: WO2016/055910 WO 20160414
- Main IPC: H01M4/1391
- IPC: H01M4/1391 ; H01M4/04 ; H01M4/505 ; H01M4/525 ; C01G53/00 ; H01M4/485 ; H01M10/052

Abstract:
A method for producing a M-carbonate precursor of a Li-M oxide cathode material in a continuous reactor, wherein M=NixMnyCozAn, A being a dopant, with x>0, y>0, 0≤z≤0.35, 0≤n≤0.02 and x+y+z+n=1, the method comprising the steps of: —providing a feed solution comprising Ni-, Mn-, Co- and A-ions, and having a molar metal content M″ feed, —providing an ionic solution comprising either one or both of a carbonate and a bicarbonate solution, the ionic solution further comprising either one or both of Na- and K-ions, —providing a slurry comprising seeds comprising M′-ions and having a molar metal content M′ seeds, wherein M′=Nix′Mny′Coz′A′n′, A′ being a dopant, with 0≤x′≤1, 0≤y′≤1, 0≤z′≤1, 0≤n′≤1 and x′+y′+z′+n′=1, and wherein the molar ratio M′ seeds/M″ feed is between 0.001 and 0.1, —mixing the feed solution, the ionic solution and the slurry in the reactor, thereby obtaining a reactive liquid mixture, —precipitating a carbonate onto the seeds in the reactive liquid mixture, thereby obtaining a reacted liquid mixture and the M-carbonate precursor, and —separating the M-carbonate precursor from the reacted liquid mixture.
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