The electrochemical cell has an anode, a cathode, and a solid electrolyte layer. The cathode contains a perovskite oxide expressed by the general formula ABO3 and includes at least one of Sr and La at the A site as a main component. The solid electrolyte layer is disposed between the anode and the cathode. The cathode includes a solid electrolyte layer-side region within 3 μm from a surface of the solid electrolyte layer side. The solid electrolyte layer-side region includes a main phase which is configured by the perovskite oxide and a second phase which is configured by Co3O4 and (Co, Fe)3O4. An occupied surface area ratio of the second phase in a cross section of the solid electrolyte layer-side region is less than or equal to 10.5%.