Invention Grant
- Patent Title: Dihydrocarbyl-silyl-bridged-1,3 disubstituted-2-indenyl metallocene complexes for olefin polymerization
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Application No.: US16500658Application Date: 2018-04-04
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Publication No.: US11427608B2Publication Date: 2022-08-30
- Inventor: Nicolaas Hendrika Friederichs , Antonio Vittoria , Roberta Cipullo , Vincenzo Busico , Ilya Borisov , Bogdan A. Guzeev , Dmitry Y. Mladentsev , Mikhail I. Sharikov , Dmitry Uborsky , Alexander Voskoboynikov , Hendriksen Coen
- Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
- Applicant Address: NL Bergen op Zoom
- Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee Address: NL Bergen op Zoom
- Agency: Cantor Colburn LLP
- Priority: EP17164676 20170404
- International Application: PCT/EP2018/058622 WO 20180404
- International Announcement: WO2018/185170 WO 20181011
- Main IPC: C07F17/00
- IPC: C07F17/00 ; C08F4/6592 ; C08F210/16 ; C08F4/659 ; C08F10/00

Abstract:
The invention relates to a metallocene complex according to formula (A): wherein R1 is selected from C1-C10 alkyl, C6-C20 aryl, C7-C20 aralkyl groups, and C1-C10 alkoxy groups, wherein R2 is selected from H, C1-C10 alkyl; wherein R3-R6, R10 are independently selected from H, C1-C10 alkyl, C6-C10 aryl, and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ringstructure; wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M, z is the number of X groups and equals the valence of M minus 2, and wherein each R7 independently is selected from C1-C6 alkyl or aryl groups. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerization process of olefinic monomers.
Public/Granted literature
- US20210115080A1 DIHYDROCARBYL-SILYL-BRIDGED-1,3 DISUBSTITUTED-2-INDENYL METALLOCENE COMPLEXES FOR OLEFIN POLYMERIZATION Public/Granted day:2021-04-22
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