A method of synchronizing a cross-compound generator system on one or more turning gears during startup includes determining, via a notch monitor controller, first and second angular velocities, respectively, of a first and a second rotor. The method also includes simultaneously exciting, via the notch monitor controller, the first and second rotors to attain electromechanical coupling therebetween. The method further includes determining, via the notch monitor controller, a value of a time at which a calibration value of an offset is a constant value, where the offset is representative of a phase alignment of the first rotor relative to the second rotor, and where the offset is indicative of a successful electromechanical coupling therebetween. The method also includes disengaging the one or more turning gears from the cross-compound generator system.