A double 6-way valve for a vehicle cooling system provides various modes, reduces the number of parts of the cooling system, and improves packaging, compared to a conventional cooling system. The double 6-way valve includes: an upper housing including a plurality of upper nipples disposed at equal intervals on an outer circumference surface thereof; a lower housing stacked under the upper housing and including a plurality of lower nipples disposed at equal intervals on an outer circumference surface thereof; an upper hub rotatably mounted within the upper housing; a lower hub rotatably mounted within the lower housing and stacked under the upper hub; and a driving apparatus to rotate the upper hub and the lower hub.