The method comprises: a user terminal initiating an authentication request to a target server and providing device information of the user terminal, and the target server receiving the authentication request and generating a temporary session, and sending a temporary session ID and the device information to a quantum key allocation network; the quantum key allocation network searching for a wearable device bound to the user terminal, and sending the temporary session ID to the wearable device; the wearable device collecting biological recognition information of a user, and sending the biological recognition information to the quantum key allocation network; and the quantum key allocation network matching the biological recognition information with pre-stored biological recognition information, wherein if matching is successful, an authentication result is sent to the target server, and then the target server sends the authentication result to the user terminal.