The present invention provides a polyimide composite having a structural formula of PI/Fe3O4-(β-CD-Ada)x, wherein x=3-5. One aspect of the invention provides a polyimide composite. By introducing Fe3O4 as a host material of an electromagnetic wave absorption material and introducing a guest material, a repairing property of the material itself is imparted by an interaction between the host material and the guest material. Therefore, the polyimide composite has an electromagnetic radiation shielding property and a self-repairing property.