An air-assisted electrostatic ultrasonic atomization nozzle includes an intake sleeve, a Laval tube, a resonant body and a jet element body. The left end of the intake sleeve is equipped with the air intake, and the right end of the air inlet sleeve is connected with the left end of the Laval tube. The right end of the Laval tube is connected with the left end of the resonant body. The right end of the resonant body is connected with the left end of the jet element body. The sealing surface of the resonant tube is arranged between the resonant body and the jet element body. The sealing surface of the resonant tube obstructs the gas-liquid in the axial direction of the resonant body and the jet element body. The resonant body has a resonant chamber, and the sidewall of the resonant body is equipped with a V-shaped resonant tube.