The positive electrode active material with lithium composite oxide A containing W and Ni and W-free lithium composite oxide B containing Ni. Regarding the lithium composite oxide A, the proportion of Ni relative to the total moles of metal elements except for lithium is 30 to 60 mol %, 50% particle size D50 is 2 to 6 μm, 10% particle size D10 is 1.0 μm or more, and 90% particle size D90 is 6.8 μm or less. Regarding the lithium composite oxide B, the proportion of Ni relative to the total moles of metal elements except for lithium is 50 to 95 mol %, 50% particle size D50 is 10 to 22 μm, 10% particle size D10 is 7.0 μm or more, and 90% particle size D90 is 22.5 μm or less. The mass ratio of the lithium composite oxide B to the lithium composite oxide A is 1:1 to 5.7:1.