An intrinsically safe (IS) luminaire disposed in a hazardous environment provides visible light and serves as a primary, auxiliary, back-up, and/or charging source of IS DC power for external devices disposed in the hazardous environment, such as process control devices and equipment. The luminaire includes a power converter that converts received power into DC power, an IS barrier that converts the DC power into IS DC power native to or utilized by a recipient external device, and a power distribution port via which IS DC power is delivered to the external device. In some configurations, the luminaire monitors communicates statuses, alerts, and/or other information corresponding to delivering IS DC power to one or more external devices to a host and/or portable communication device. The luminaire may include multiple IS barriers of same and/or different IS ratings, and may dynamically control activation/deactivation of the IS barriers and/or usages thereof.