There is disclosed a method of coating textile fibers, the method comprising applying, on the external surface of textile fibers, a pre-treated oil-in-water emulsion comprising: (i) an aqueous phase containing water; and (ii) a pre-treated oil phase containing at least one reactive condensation-curable film-forming amino-silicone pre-polymer that, subsequent to condensation curing optionally in presence of additional reactants, forms an amino-silicone coat. The pre-treated reactive oil phase includes at least one pre-treated reactant or pre-treated pre-polymer. An aqueous dispersion containing particles of a hydrophilic polymeric material is then applied to the amino-silicone coat, so as to form a polymeric layer thereon. At least one of the oil-in-water emulsion forming a first coat and of the aqueous dispersion forming a second coat may further contain a plurality of sub-micronic pigment particles dispersed therein. Suitable compositions and kits including the same are also disclosed, as well as fibers coated thereby.