A method for programming the energy storage device in power-gas coupling system based on reliability constraints is provided. The method includes: obtain the parameters and operation condition of each equipment of the power-gas coupling system in a year; determine the different operating states of the system. A programming model of the energy storage device based on reliability constraints is constructed based on the operating state of the system, and benders decomposition algorithm is adopted to calculate the programming model, so that the programming scheme of the energy storage device is obtained. Considering not only the economy but also the reliability of the system, which is more accurate, comprehensive and effective than the previous programming method; the present invention is of great significance to improve the reliability of the electric power system and ensure the safe and reliable operation of the electric power system.