Invention Grant
- Patent Title: Process for the production of dialkyl terephthalate
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Application No.: US16981964Application Date: 2019-03-28
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Publication No.: US11591283B2Publication Date: 2023-02-28
- Inventor: Simon William Breeden , James Hanley Clark , Thomas James Farmer , Duncan James MacQuarrie , Con Robert McElroy , Joseph Kolawole Ogunjobi , David William Thornthwaite
- Applicant: Conopco, Inc.
- Applicant Address: US NJ Englewood Cliffs
- Assignee: Conopco, Inc.
- Current Assignee: Conopco, Inc.
- Current Assignee Address: US NJ Englewood Cliffs
- Agency: Foley & Lardner LLP
- Priority: EP18168062 20180418
- International Application: PCT/EP2019/057916 WO 20190328
- International Announcement: WO2019/201569 WO 20191024
- Main IPC: C07C67/347
- IPC: C07C67/347 ; B01J21/16 ; B01J37/30 ; C07C69/82

Abstract:
A process for preparing dialkyl terephalate comprising the following steps:—i) providing furan-2,5-dicarboxylate; ii) esterifying the furan-2,5-dicarboxylate with alcohol to form furan-2,5-carboxylic acid dialkyl ester; iii) reacting the furan-2,5-carboxylic acid dialkyl ester with ethylene under Diels Alder conditions, elevated temperature and pressure and in the presence of a catalyst such that dialkyl terephthalate is produced; wherein the Diels-Alder reaction is free from solvent; wherein the catalyst comprises a clay comprising metal ions and having Lewis acidity.
Public/Granted literature
- US20210122698A1 PROCESS FOR THE PRODUCTION OF DIALKYL TEREPHTHALATE Public/Granted day:2021-04-29
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