Invention Grant
- Patent Title: ZnO nanoparticle coated exfoliated graphite composite, method of producing composite and use in Li-ion battery
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Application No.: US16604879Application Date: 2017-12-21
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Publication No.: US11594723B2Publication Date: 2023-02-28
- Inventor: Olga Isakin , Kerstin Schindler , Ralph Schneider , Ralf Moos , Monika Willert-Porada
- Applicant: ECKART GmbH
- Applicant Address: DE Hartenstein
- Assignee: ECKART GmbH
- Current Assignee: ECKART GmbH
- Current Assignee Address: DE Hartenstein
- Agency: Fitch, Even, Tabin & Flannery LLP
- Priority: EP17000646 20190413
- International Application: PCT/EP2017/084117 WO 20171221
- International Announcement: WO2018/188772 WO 20181018
- Main IPC: H01M4/36
- IPC: H01M4/36 ; H01M4/48 ; H01M4/587 ; H01M10/0525 ; H01M4/02

Abstract:
Composites comprising an exfoliated graphite support material having a degree of graphitization g in an range of 50 to 93%, obtained by XRD Rietveld analysis, which is coated with ZnO nanoparticles. These composites are produced by three different methods: A) (syn) the method comprises the following consecutive steps: i) a Zn(II)salt is dissolved in a solvent ii) graphite and a base are added simultaneously iii) the mixture is stirred under impact of ultrasound iv) the solvent is removed from the suspension or B) (pre) the method comprises the following consecutive steps: i) graphite is suspended in a solvent and exfoliated via impact of ultrasound ii) a Zn(II)salt and a base are added simultaneously forming nano-ZnO particles iii) the mixture is stirred iv) the solvent is removed from the suspension or C) (post) the method comprises the following steps: i) a Zn(II)salt and a base are mixed in a solvent in a first reactor forming nano-ZnO particles ii) graphite is exfoliated via impact of ultrasound in a second reactor iii) both suspensions of i) and ii) are mixed together iv) after step iii) the solvent is removed from the suspension. These coated composites may be tempered in a further step and again coated and again tempered.
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