Systems and methods for potassium enhancing silicon-containing anodes for improved cyclability
Abstract:
Various methods and techniques for enhancing a silicon-containing anode for a battery cell are presented. The methods may include providing a silicon-containing anode having reversible electrochemical capabilities including a silicon-containing material and an anode material compatible with a lithium-ion battery chemistry having porous and conductive mechanical properties. The methods may also include enriching a surface layer of the silicon-containing anode with sodium ions to intersperse the sodium ions between silicon atoms of the silicon-containing material. The methods may also include displacing the sodium ions with potassium ions to form a compression layer in the silicon-containing anode. The potassium ions may place the silicon atoms of the silicon-containing material in a pre-compressive state to counteract internal stress exerted on the silicon-containing material.
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