Invention Grant
- Patent Title: Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
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Application No.: US17173850Application Date: 2021-02-11
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Publication No.: US11613593B2Publication Date: 2023-03-28
- Inventor: Jo Ann M. Canich , Jian Yang , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Oleg V. Samsonov , Georgy P. Goryunov
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Agency: ExxonMobil Chemical Patents Inc.
- Main IPC: C07F17/00
- IPC: C07F17/00 ; C08F4/6592 ; C08F4/642 ; C08F4/659 ; C08F10/02 ; C08F10/06

Abstract:
Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values. M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R1, R1′, R3, R3′, R4, R4′, R7 and R7′ are hydrogen. R5, R5′, R6, and R6′ are independently a C1-C10, optionally substituted, hydrocarbyl group, or R5 and R6 and/or R5′ and R6′ are bonded together to form an optionally substituted hydrocarbyl ring structure.
Public/Granted literature
- US20210269561A1 Ansa-Bis(Inden-2-yl) Catalysts For Producing Vinylidene-Terminated Polyalphaolefins Public/Granted day:2021-09-02
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