A photovoltaic Bluetooth headset compartment is provided, comprising: a bottom shell, an upper cover flip-connected with the bottom shell, an inner support assembled on the bottom shell, a photovoltaic panel assembled on an outside of the upper cover, a circuit board assembled in the bottom shell and, a storage battery assembled in the bottom shell and electrically connected to the circuit board, wherein the upper cover is provided with a first spring pin of which one end is electrically connected to the photovoltaic panel and the other end extends from the upper cover, and the inner support is provided with a spring pin contact point electrically connected to the circuit board; and after the upper cover is closed, the first spring pin is inserted into a spring pin contact point and the photovoltaic panel charges the storage battery.