The present disclosure relates to a magnetic assembly structure which utilizes a magnetic attraction or repulsion effect generated by two magnetic components to make two buckle structures automatically engaged to each other. The magnetic assembly structure of the present disclosure has a first main body and a second main body, and via the hardware design of disposing magnetic components and buckle structures respectively on the first main body and the second main body, the first and second main bodies rotate in respect to each other due to the magnetic attraction or repulsion effect, so as to efficiently engage the two buckle structures each other. Thus, it actually eases the installation and uninstallation of the appliance to which the magnetic assembly structure is applied, and the costs of installation and consuming time are reduced.