Invention Grant
- Patent Title: Halftone phase shift-type photomask blank, method of manufacturing thereof, and halftone phase shift-type photomask
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Application No.: US17017336Application Date: 2020-09-10
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Publication No.: US11644743B2Publication Date: 2023-05-09
- Inventor: Takuro Kosaka , Keisuke Sakurai
- Applicant: Shin-Etsu Chemical Co., Ltd.
- Applicant Address: JP Tokyo
- Assignee: SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee: SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Birch, Stewart, Kolasch & Birch, LLP
- Priority: JP 2019176829 2019.09.27
- Main IPC: G03F1/32
- IPC: G03F1/32

Abstract:
A halftone phase shift-type photomask blank including a transparent substrate, and a halftone phase shift film formed on the substrate, and including at least one layer composed of silicon, nitrogen and oxygen is provided. The halftone phase shift film has a phase shift of at least 150° and up to 200° and a transmittance of at least 20%, with respect to exposure light having a wavelength of up to 200 nm, and a film surface having a surface roughness RMS of up to 0.8 nm, and an in-plane variation of transmittance calculated from the maximum transmittance Tmax and the minimum transmittance Tmin within a mask pattern forming area by the expression: (Tmax−Tmin)/(Tmax+Tmin)×100 is up to 2%.
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