A fluid sampling tool and method for fluid sampling in an ultra-tight or tight formation. The tool may include a packer assembly that includes one or more inflatable packers and one or more exhaust ports, a multi-chamber section that includes one or more sample chambers, and at least two storage sections that each contain a storage tank, wherein each storage tank holds a stimulation fluid. A method for performing a stimulation operation that includes disposing a fluid sampling tool into a well, moving the fluid sampling tool to a zone of interest, and isolating the zone of interest with a packer assembly on the fluid sampling tool. The method may further include performing a first pressure draw down and a first pressure build up, performing an injectivity test, and performing a sampling process.