A macro-molecular leakage-free self-adhering aluminum foil has two layers of aluminum foil compounded using a PET film, and the other surfaces of each layer coated with a modified PE adhesive layer respectively; or air gaps in one surface or two surfaces are filled with nano-aluminum to form a permeable air gap-free surface. The foil has advantages: 1, high folding resistance, fatigue resistance and strength 2, wrapping self-adhering performance is good, and stripping strength formed after adhesion is several times as high as that of the prior art; 3, air gaps in the surface of the aluminum foil filled with nano-aluminum powder result in improved compactness; manufacture from low-grade aluminum foil, and so that rolling precision requirements are lowered, and manufacturing cost reduced; 4, insulating strength is high, shielding effect is good, the return loss phenomenon is avoided, and tensile strength is good.