A duplex stainless steel having excellent carbon dioxide corrosion resistance, excellent sulfide stress corrosion cracking resistance, and excellent sulfide stress cracking resistance. The duplex stainless steel comprises, by mass %, C: 0.03% or less, Si: 1.0% or less, Mn: 0.10 to 1.5%, P: 0.030% or less, S: 0.005% or less, Cr: 20.0 to 30.0%, Ni: 5.0 to 10.0%, Mo: 2.0 to 5.0%, Cu: 2.0 to 6.0%, N: less than 0.07%, at least one selected from Al: 0.05 to 1.0%, Ti: 0.02 to 1.0%, and Nb: 0.02 to 1.0%, and the balance being Fe and unavoidable impurities, and has a structure that is 20 to 70% austenite phase, and 30 to 80% ferrite phase in terms of a volume fraction.