A waste hydrogen recovery device of an evaluation device of a hydrogen refueling station includes: a buffer container connected to a discharge pipeline of the evaluation device; a flow path switching valve installed at a hydrogen supply side of the hydrogen refueling station and installed to selectively form a flow path flowing hydrogen from one of a hydrogen supply source or the buffer container into the hydrogen refueling station; and a controller provided to control a tank protection valve installed between an inflow pipeline and a discharge pipeline of the evaluation device, and the controller further provided to control a hydrogen tank, a discharge valve installed on the discharge pipeline, the flow path switching valve, and a compressor of the hydrogen refueling station.