The invention relates to a material and its method for rapidly eluting ammonium ions and soluble metal cations in an ionic rare earth ore leaching site, which comprises the following steps: 1) Ferrous sulfate is dissolved in water as an eluant; 2) Take the soil sample from the closed leaching site of ionic rare earth ore to make an eluting column, use the above-mentioned eluent to elute, more than 95% water-soluble and exchangeable ammonium ions in the soil sample are eluted, while more than 90% of the residual rare earths in the soil sample are exchanged into the eluent, which can quickly achieve the purpose of eluting ammonium ions in the leaching site and recovering the residual rare earths, and is beneficial to the soil remediation for the leaching site.