Invention Grant
- Patent Title: Hydroformylation process
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Application No.: US17289492Application Date: 2019-11-14
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Publication No.: US11691936B2Publication Date: 2023-07-04
- Inventor: Michael A. Brammer , Jason F. Giles , Glenn A. Miller
- Applicant: Dow Technology Investments LLC
- Applicant Address: US MI Midland
- Assignee: Dow Technology Investments LLC
- Current Assignee: Dow Technology Investments LLC
- Current Assignee Address: US MI Midland
- International Application: PCT/US2019/061509 2019.11.14
- International Announcement: WO2020/112373A 2020.06.04
- Date entered country: 2021-04-28
- Main IPC: C07C45/50
- IPC: C07C45/50 ; B01J31/24 ; B01J31/22

Abstract:
Embodiments of the present invention are directed to processes to improve rhodium accountability in continuous liquid recycle hydroformylation processes. In some embodiments, a process comprises contacting in a reaction zone reactants comprising mixed C8 olefins or mixed C9 olefins, hydrogen, and carbon monoxide in the presence of a catalyst comprising rhodium and an organomonophosphite ligand to form a reaction fluid, wherein the reaction fluid is introduced to a strip gas vaporizer to produce a product stream and a vaporizer tails stream, and wherein the vaporizer tails stream comprises at least 1.2 percent by weight C8 internal olefins or at least 1.3 percent by weight C9 internal olefins.
Public/Granted literature
- US20210387935A1 HYDROFORMYLATION PROCESS Public/Granted day:2021-12-16
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