The present invention relates to an insole containing one or more cavities, wherein said one or more cavities contain a component capable of a physiochemical reaction, as well as articles of footwear containing the insole and methods of making the insole. The invention also relates to methods of heat transfer between an article of footwear and a foot of a wearer of the article of footwear, the method including priming the insole, wherein the priming initiates the physiochemical reaction.