A method of estimating a clock frequency offset in a mobile device relative to a clock frequency of a controller within a UWB network comprises (a) determining, for each of a plurality of anchors, an anchor clock frequency offset relative to the controller clock frequency, (b) broadcasting an anchor data packet from each anchor, the anchor data packet including the respective anchor clock frequency offset, (c) receiving at least one anchor data packet at the mobile device, (d) estimating a mobile device clock frequency offset relative to the anchor clock frequency of the anchor from which the at least one anchor data packet was received, and (e) estimating the clock frequency offset in the mobile device based on the estimated mobile device clock frequency offset and the anchor clock frequency offset included in the at least one received anchor data packet. Furthermore, a TDoA-based localization method and a TDoA-based localization system are described.