The present application relates to the technical field of the research on energetic composite materials, and in particular to a device and a method for controlling transverse and longitudinal stress waves during the curing process of energetic composite materials. The device for controlling transverse and longitudinal stress waves comprises a curing vessel containing an energetic composite materials to be cured; a vertical exciter that is vertically incident to the curing vessel; and a plurality of oblique exciters which are arranged around the vertical exciter and obliquely incident to the curing vessel, wherein the oblique exciters have inclination angles between a first critical angle and a second critical angle. By means of incident transverse and longitudinal waves, the internal radial residual stress and the internal axial residual stress are reduced and homogenized, so as to improve stability and mechanical property of the energetic composite materials during curing.