Invention Grant
- Patent Title: Catalyst mixture
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Application No.: US17276437Application Date: 2019-09-17
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Publication No.: US11767376B2Publication Date: 2023-09-26
- Inventor: Raffaele Bernardo , Gerardus Van Doremaele , Wouter Van Meerendonk , Peter Windmuller
- Applicant: ARLANXEO NETHERLANDS B.V.
- Applicant Address: NL Geleen
- Assignee: ARLANXEO NETHERLANDS B.V.
- Current Assignee: ARLANXEO NETHERLANDS B.V.
- Current Assignee Address: NL Geleen
- Agency: Norris McLaughlin PA
- Priority: EP 195257 2018.09.18
- International Application: PCT/EP2019/074869 2019.09.17
- International Announcement: WO2020/058267A 2020.03.26
- Date entered country: 2021-03-15
- Main IPC: C08F4/6592
- IPC: C08F4/6592 ; C08F236/20 ; C08L23/08 ; C08F4/659 ; C08F210/18

Abstract:
The present invention relates to a catalyst mixture containing at least one metal complex according to the formula (1)
CyLMZp (1),
and at least one metal complex according to the formula (2)
InLMZp (2),
wherein
Cy is a substituted cyclopentadienyl ligand that contains the substituents R1, R2 and 3 additional methyl groups, wherein
R1 means H, halogen or a C3-C20 substituent and
R2 means a C1-C20 substituent,
In is an indenyl ligand, optionally substituted with one or more substituents R3, wherein the one or more substituents R3 mean independently C1-C20 hydrocarbyl substituents,
and independently for each formula (1) and (2)
M is a group 4 metal
Z independently is an anionic ligand,
p is number of 1 to 2, preferably 2, and
L is an amidinate ligand of the formula (3)
wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom.
CyLMZp (1),
and at least one metal complex according to the formula (2)
InLMZp (2),
wherein
Cy is a substituted cyclopentadienyl ligand that contains the substituents R1, R2 and 3 additional methyl groups, wherein
R1 means H, halogen or a C3-C20 substituent and
R2 means a C1-C20 substituent,
In is an indenyl ligand, optionally substituted with one or more substituents R3, wherein the one or more substituents R3 mean independently C1-C20 hydrocarbyl substituents,
and independently for each formula (1) and (2)
M is a group 4 metal
Z independently is an anionic ligand,
p is number of 1 to 2, preferably 2, and
L is an amidinate ligand of the formula (3)
wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom.
Public/Granted literature
- US20220056162A1 CATALYST MIXTURE Public/Granted day:2022-02-24
Information query
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