The present disclosure provides a printable curved-surface perovskite solar cell, including a curved-surface conductive substrate, a porous electron transport layer, a porous insulation layer, a porous back electrode layer and a perovskite filler. The curved-surface conductive substrate includes a curved-surface transparent substrate and a conductive layer deposited on the curved-surface transparent substrate. The porous electron transport layer, the porous insulation layer and the porous back electrode layer are sequentially deposited on the conductive layer from bottom to top. The perovskite filler is filled in pores of the porous electron transport layer, the porous insulation layer and the porous back electrode layer. The present disclosure further provides a method for preparing the printable curved-surface perovskite solar cell.