- Patent Title: Method for producing modified polytetrafluoroethylene, method for producing modified polytetrafluoroethylene powder, and method for producing stretched porous material
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Application No.: US17021129Application Date: 2020-09-15
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Publication No.: US11780943B2Publication Date: 2023-10-10
- Inventor: Shinya Higuchi , Shiro Ebata , Takehiro Kose
- Applicant: AGC Inc.
- Applicant Address: JP Tokyo
- Assignee: AGC Inc.
- Current Assignee: AGC Inc.
- Current Assignee Address: JP Tokyo
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: JP 18087280 2018.04.27
- Main IPC: C08F214/26
- IPC: C08F214/26 ; C08F2/10 ; C08J3/16

Abstract:
To provide a method for producing modified polytetrafluoroethylene, in which formation of a fluorinated oligomer as a by-product is little. A method for producing modified polytetrafluoroethylene which contains substantially no C6-34 fluorinated oligomer containing hydrophilic functional groups and which contains substantially no fluorinated surfactant, the method comprising conducting copolymerization of tetrafluoroethylene and a monomer having a polar group, in a liquid dispersion 1 comprising a polymer containing units derived from a non-fluorinated monomer and an aqueous medium, or in a solution 2 obtainable by mixing at least one member selected from the group consisting of a polyalkylene oxide compound and a hydrocarbon-containing surfactant, with an oxidizing agent, in an aqueous medium, under such a condition that the amount of the monomer having a polar group to be used, is at most 0.150 mass % to the whole amount of tetrafluoroethylene, to obtain modified polytetrafluoroethylene.
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