Invention Grant
- Patent Title: Amphiphilic block copolymer surfactant for attenuating acid reactivity during acid stimulation of carbonate rich reservoirs
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Application No.: US17452913Application Date: 2021-10-29
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Publication No.: US11781057B2Publication Date: 2023-10-10
- Inventor: Sivaprakash Shanmugam , Amy J. Cairns , Mohammed Sayed
- Applicant: ARAMCO SERVICES COMPANY
- Applicant Address: US TX Houston
- Assignee: SAUDI ARABIAN OIL COMPANY
- Current Assignee: SAUDI ARABIAN OIL COMPANY
- Current Assignee Address: SA Dhahran
- Agency: Osha Bergman Watanabe & Burton LLP
- Main IPC: C09K8/74
- IPC: C09K8/74 ; C09K8/54 ; C08F293/00 ; E21B43/27 ; C09K8/60

Abstract:
A composition for treating a formation includes a surfactant including an amphiphilic block copolymer having a first block and a second block and an acid. The amphiphilic block copolymer is a reaction product of a first monomer and a second monomer via a reversible addition-fragmentation chain transfer polymerization (RAFT) in a two-step reaction using a chain transfer agent (CTA) and a radical initiator. The surfactant favors adsorption onto a surface of the formation such that a temporary barrier is formed, thereby attenuating a reaction rate between the acid and the formation.
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