A solar panel for pitched roof and construction method of the solar panel are disclosed. The solar panel includes a substrate, a first bonding layer, an insulating layer, a second bonding layer, a solar cell module layer, a third bonding layer, a brightness enhancement film layer, a fourth bonding layer and a transparent fluorine element film layer from bottom to top. Since the peripheral fixing area of the substrate has fixing holes for fixing purposes, the solar panels of the present invention can replace the existing asphalt shingles and be applied on the pitched roof, and have the characteristics such as water removal, moisture resistance, extreme temperature resistance and windproof. The solar panel can not only provide renewable energy, but its neat appearance can also increase the beauty of the pitched roof.