- Patent Title: Fluororesin, fluororesin particles, and methods for producing these
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Application No.: US17280624Application Date: 2019-09-27
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Publication No.: US11807702B2Publication Date: 2023-11-07
- Inventor: Shohei Yumino , Tomoya Shimono , Kota Sakaguchi , Tomonari Nagai , Kazunari Iwanaga , Masao Tanabiki , Toru Doi
- Applicant: TOSOH CORPORATION
- Applicant Address: JP Shunan
- Assignee: TOSOH CORPORATION
- Current Assignee: TOSOH CORPORATION
- Current Assignee Address: JP Shunan
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: JP 18183594 2018.09.28 JP 19027318 2019.02.19 JP 19037005 2019.02.28 JP 19171553 2019.09.20
- International Application: PCT/JP2019/038144 2019.09.27
- International Announcement: WO2020/067421A 2020.04.02
- Date entered country: 2021-03-26
- Main IPC: C08F24/00
- IPC: C08F24/00

Abstract:
The present invention relates to resin particles including a residue unit represented by the following general formula (1) and having a volume average particle diameter equal to or more than 5 μm and equal to or less than 2000 μm, and a method for producing thereof. Furthermore the present invention relates to a fluororesin comprising a residue unit represented by a general formula (1) and having a weight average molecular weight Mw in a range of 5×104 to 3×105, and a yellow index of a heat-melted molded product (thickness 3 mm) after 24 h at 280° C. of equal to or less than 6, and a method for producing thereof.
In the formula (1), Rf1, Rf2, Rf3, and Rf4 are each independently one of the groups consisting of a fluorine atom, a linear perfluoroalkyl group having 1 to 7 carbon atoms, a branched perfluoroalkyl group having 3 to 7 carbon atoms, or a cyclic perfluoroalkyl group having 3 to 7 carbon atoms. The perfluoroalkyl group may have an ethereal oxygen atom. Further, Rf1, Rf2, Rf3, and Rf4 may be linked to one another to form a ring having 4 or more and 8 or less carbon atoms, and the ring may include an ethereal oxygen atom.
In the formula (1), Rf1, Rf2, Rf3, and Rf4 are each independently one of the groups consisting of a fluorine atom, a linear perfluoroalkyl group having 1 to 7 carbon atoms, a branched perfluoroalkyl group having 3 to 7 carbon atoms, or a cyclic perfluoroalkyl group having 3 to 7 carbon atoms. The perfluoroalkyl group may have an ethereal oxygen atom. Further, Rf1, Rf2, Rf3, and Rf4 may be linked to one another to form a ring having 4 or more and 8 or less carbon atoms, and the ring may include an ethereal oxygen atom.
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