Apparatus and methods for envelope alignment calibration in radio frequency (RF) systems are provided. In certain embodiments, calibration is performed by providing an envelope signal that is substantially triangular along an envelope path, and by providing an RF signal to a power amplifier along an RF signal path. Additionally, an output of the power amplifier is observed to generate an observation signal using an observation receiver. The observation signal includes a first peak and a second peak, and a delay between the envelope signal and the RF signal is controlled based on relative size of the peaks of the observation signal to one another.