A positive active material includes a secondary particle in which a plurality of primary particles is agglomerated. The positive active material is composed of, in which a compound containing nickel, lithium, and oxygen. An average angle between a reference line connecting a center portion of the secondary particle and a center portion of the primary particle provided at the outermost portion of the secondary particle and a particle orientation line penetrating the center portion of the primary particle provided at the outermost portion of the secondary particle and extending in parallel to an orientation direction of the primary particles is 12.2° or less. A concentration of the nickel in the compound is 59 mol % or more. The compound further includes an added metal composed of a different element from the nickel and the lithium. The added metal includes one or more of boron (B) and tungsten (W).