The present invention relates to a process for purifying a composition comprising a hydrohalocarbon B comprising the steps of: i) providing a composition A1 comprising a hydrohalocarbon B and at least one impurity C different from said hydrohalocarbon B, ii) compressing said composition A1, and optionally cooling it, so as to obtain said hydrohalocarbon B in liquid form in order to form a liquid stream A2 comprising said hydrohalocarbon B, iii) distilling said stream A2 obtained in step ii) in order to form and recover a stream A3 comprising said hydrohalocarbon B, characterized in that step iii) is carried out in a pressurized distillation device comprising one or more rotating packed beds.